academicschemistry

We found 27 articles

The case for physical chemistry
For many years in academia, I have been teaching courses in what I consider the "Holy Grail of Chemistry" - Physical Chemistry (which is composed of Quantum Chemistry, Statistical Thermodynamics, Kinetics, and Chemical Dynamics. In these courses, physics, mathematics, biology, and chemistry blend together in an exquisite way to provide a ...
Intermolecular forces: a basic, ground-up approach
Intermolecular forces (IMFs) are “electrostatic” interactions between molecules – a result of all the charges floating around and interacting in the system. IMFs influence the properties of substances that we can observe and interact with – for example, the phase of the substance or its boiling point.
The hydrophobic effect, explained
If we had to pick one go-to answer to explain as many things as possible in biochemistry, it would probably be “the hydrophobic effect.” It’s responsible for protein structure and function, cell membrane organization, and the distribution of drugs and metabolites. It’s often an important consideration in drug design. But what is it, and how does ...
How to use the ideal gas law
While you might not think about it very often, gases are everywhere around us, from the air you breathe to the natural gas you might use to heat your home. To use gases safely and effectively, chemists use the ideal gas law to understand how much gas is in containers and pipes.
Why does chemistry seem so difficult?
I have greeted over 1,000 students to my classroom throughout the 20+ years of teaching AP Chemistry, and the number one question I hear is “Why is chemistry so hard?” I have several responses to that question that I have offered to my students. But first, I want you to read each bullet below and notice which one resonates with you:
Chromatography: purifying your understanding
Maybe you were studying for the MCAT or just in your college chemistry lab when it dawned on you: why are there so many different types of chromatography? What do they have in common and what are their differences?
How to solve an empirical formula problem
In this blog post, we will review how to determine the empirical formula of a compound using the mass percentages of the elements from which it is formed.
Quantum numbers
In this blog post, we explore the four quantum numbers, which allow us to describe the properties of each electron within an atom. According to the Pauli Exclusion Principle, no two electrons can share the same combination of quantum numbers. A carbon atom has six electrons, for example, and each of these electrons can be described by one of six ...
A painless introduction to VSEPR theory
Today we will discuss VSEPR (pronounced “vesper”), which stands for valence-shell electron-pair repulsion. The basis of VSEPR is that the electrons in bonds and lone pairs repel each other. To minimize the instability that results from these repulsions, a molecule will adopt the shape that places electron groups as far apart as possible. VSEPR ...
Tips for success in organic chemistry courses
Organic chemistry is historically considered a “weed-out” class for pre-medical students and often the cause of much frustration for students. After spending 3 years during college serving as a teaching assistant and tutor for organic chemistry courses at my undergraduate university, here are some tips for studying for your organic chemistry ...
How to balance redox reactions in acidic and basic solutions
Balancing redox reactions is an essential skill for the Chemical and Physical Foundations section of the MCAT, the GRE Chemistry Subject Test, and the AP Chemistry Exam. Today, we will learn how to use the half-cell method for balancing redox reactions in acidic and basic solutions. We will first balance a redox reaction in acidic solution, then ...
S’more fun: simplifying limiting reactants using chocolate
Stoichiometry: it’s the bane of many chemistry students’ studies. It’s so easy to get tangled up in a jumble of numbers without any idea of what’s actually going on.
I just want to be a doctor, so does organic chemistry really matter?
Imagine: you’ve made it through your first semester or two of undergrad and weathered all the storms that come with this transition. And, now you find yourself facing a dreaded academic giant that has stricken fear in the hearts of scores of pre-medical students. A chemistry course unlike any other. If you are anything like most pre-medical ...
High school chemistry: What is it? Can I be good at it?
The word “chemistry” inspires so many emotions. To some, it brings about the excitement of mixing together glowing liquids and crafting the perfect radioactive potion that, when consumed, will turn you into the Incredible Hulk. To others, it’s discombobulated numbers and letters on a piece a paper in a classroom, a concatenation that strikes fear ...
So, what is chemical engineering for, anyway?
Chemical engineering is a comprehensive and vast field of study with far-reaching impact. I have been a practicing chemical engineer in the biotechnology industry for the last 5 years, and prior to that, I earned my doctorate in chemical engineering at the University of Wisconsin, Madison. Over the last 10 years, I have seen the evolution and ...
Complex solution composition problems: knowing where to start
Thanksgiving dinner conversations can be uncomfortable… but solution composition problems don’t have to be! Recall that a solution is a homogenous mixture of two or more substances. Chemists have come up with many ways to describe the composition of a solution. Some ways are more appropriate than others depending on the situation.
A guide to limiting reactant problems... using sandwiches
An everyday limiting reactant problem You’re expecting company and totally forgot to go grocery shopping. What on earth will you feed your guests? Sandwiches! You have some ingredients to whip up some sandwiches. So, let’s assume you are going to go through with making these sandwiches. You need 2 slices of bread, 3 slices of meat (can’t be ...
Dimensional analysis: why the factor-label method is a lifesaver
Ever lost points on a test because you forgot to write the units? Rightfully so! Numbers have no meaning without their units of measurement. Two can be greater than 12. Three can equal one. This is all dependent on the unit of measurement being used. In your general chemistry class, you will encounter measurements of all sorts. These measurements ...
Electron configurations: a must know hack
Imagine this...you’re taking your general chemistry midterm and you’ve decided to shuffle through the exam and complete all the hard things first. You’ve totally underestimated how much time those problems were going to take you and now you have three minutes left to write the electron configuration of 10 elements. Untimed, this would be easy to ...
Formal charge: what they didn’t tell you in your chemistry class
Formal charge is the charge that a bonded atom would have if its bonding electrons were shared equally. Note:
Orgo 2 strategies: “taking home” carboxylic acid derivatives
I’ve already covered how to easily manage carboxylic acid derivative formation and manipulation using the Reactivity Hill. Say we’re tired of whatever derivative we just created and want to bring the derivative back to its parent acid (the particular acid the derivative came from). There are two ways to “take home” any acid-derivative. We can ...
Golden rules to nuclear magnetic resonance spectroscopy (NMR) analysis: part 1
Nuclear magnetic resonance spectroscopy, or NMR, is a fundamental analytical technique used by chemists to determine the structure of organic compounds. Unlike other analytical techniques, such as infrared spectroscopy or mass spectroscopy, NMR allows for the complete interpretation of molecular structure and can be quantitative.
Two ways to determine equilibrium position in organic chemistry
A common exam question that comes up in both Orgo 1 and Orgo 2 requires students to determine a reaction’s equilibrium position. The question usually looks something like this:
Orgo 1 strategies: finding and comparing alkene hydration products
We all know Orgo 1 professors love stereoisomers. Consider the equation A + B = C. Most professors expect you to fill in the question mark with all possible products and then indicate the major product(s), while other professors may provide you a potential C and then ask you if the statement is True or False.
How to get oriented to organic chemistry: 7 pillars of the course
Organic Chemistry (OChem or Orgo) seems like a scary course. But it should not be if you know what to expect. This road map is your guide to orientate yourself to Orgo1. It teaches you about the main topics covered in Orgo1 in the typical order they are taught in class. So, take a breath and sit back as you read, skim, or view the images that ...
Orgo 1 strategies: protocol for acid-base problems
Determining which of two molecules is more acidic is tricky if you haven’t yet organized those factors that influence acidity. The protocol is a method I learned from my mastermind Orgo 2 professor to keep these ideas in order when they come into conflict. Namely: Size is more important than Electronegativity, which is more important than ...
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